Only azoxystrobin was quantified after digestion with food matrix in concentration of 27 μg/kg in sample from controlled field trial and detected in two commercial samples but below the limit of quantification. Furthermore, chronic risk assessment indicated that risk is acceptable for the health of different human subpopulation groups. The current study on pesticides residues, most commonly applied on blueberries, provides for the first time an insight into their bioaccessibility under conditions that mimic physiological environment of human digestive tract. check details In recent years, global climate change and pollution of the marine environment have caused large-scale coral deaths and severe damages to coral reef ecosystems. Numerous studies have shown that coral diseases are closely related to microorganisms. And microplastics (MPs) are a potential threat to corals. In marine ecosystems, MPs are an emerging contaminant. MPs have a strong adsorption effect on pollutants in the water environment, and they are very easily colonized by microorganisms to form biofilms. Biofilms may accumulate many pathogens, increasing the probability of coral disease. However, there is no report about the composition of biofilms on the surface of microplastics in coral growth areas. In this study, nine kinds of MPs were chosen in the experiments, which are commonly found in the ocean. Four stakeout points were selected in the coral area. Biofilms were cultivated in natural environment. The composition and distribution of biofilms on the surface of the MPs were analyzed by 16 S rRNA sequencinc data for the toxicology research of MPs. In this study, fluorescent dissolved organic matter (FDOM) in real printing and dyeing wastewater (PDW) during full-scale two-stage treatment was characterized using excitation-emission matrix (EEM), apparent molecular weight (AMW) cutoff by centrifugal ultrafiltration and high-performance liquid chromatography with fluorescence detector (HPLC-FLD). EEMs of PDW during treatment were relatively invariable with two typical and dominant peaks (P1, 275/320 nm and P2, 230/340 nm). The removal rates of P1 intensity and P2 intensity were both lower than those of DOC or UVA254 during the 1st stage and 2nd stage treatment. The less then 3 kDa fraction made major contribution to DOC, UVA254, P1 and P2 intensity. The DOM fractions with different AMW exhibited different removal behaviors during the 1st stage and 2nd stage treatment. The less then 3 kDa fraction of FDOM was poorly removed by biological treatment alone. The HPLC-FLD multi-emission scan results indicated that the major part of FDOM clusters were hydrophilic and they were more difficult to remove than the transphilic and hydrophobic FDOM clusters. According to the physicochemical properties of FDOM in PDW, selective adsorption and advanced oxidation process could be prior options for PDW advanced treatment. Laboratory experiments were performed to investigate the efficiency of a simultaneous metal stabilization, persulfate oxidation and bioremediation for decontaminating polybrominated diphenyl ethers (PBDEs) and toxic metals from an actual soil polluted by the recycling activity of electronic waste. Biochar and bentonite were applied to the soil for immobilizing heavy metals (Cu, Pb, Zn and Ni). It was found that the toxicity level declined most significantly in the case of 20 g/kg biochar +20 g/kg bentonite. A low dose of persulfate (20 mmol/kg soil) was found to be suitable for oxidizing soil PBDEs and enhancing the bioavailability of PBDEs residue. Persulfate oxidation reduced the soil organic matter content, and caused dramatic decrease of bacterial density. Nevertheless, microbial activity and number recovered on the whole during 90 days of bioremediation. Finally, a degradation efficiency of 94.6% and a mineralization efficiency of 60.3% were obtained by the hybrid treatment scheme. The pyrosequencing analysis indicates that soil bacterial community changed obviously during the treatments, and there was an enrichment of PBDE-degrading populations during bioremediation relative to that of oxidized soil. Biochar is a promising agent for wastewater treatment, soil remediation, and gas storage and separation. This review summarizes recent research development on biochar production and applications with a focus on the application of biochar technology in wastewater treatment. Different technologies for biochar production, with an emphasis on pre-treatment of feedstock and post treatment, are succinctly summarized. Biochar has been extensively used as an adsorbent to remove toxic metals, organic pollutants, and nutrients from wastewater. Compared to pristine biochar, engineered/designer biochar generally has larger surface area, stronger adsorption capacity, or more abundant surface functional groups (SFG), which represents a new type of carbon material with great application prospects in various wastewater treatments. As the first of its kind, this critical review emphasizes the promising prospects of biochar technology in the treatment of various wastewater including industrial wastewater (dye, battery manufacture, and dairy wastewater), municipal wastewater, agricultural wastewater, and stormwater. Future research on engineered/designer biochar production and its field-scale application is discussed. Based on the review, it can be concluded that biochar technology represents a new, cost effective, and environmentally-friendly solution for the treatment of wastewater. Magnetic ferrite/biochar composites are a kind of promising adsorbents due to their high adsorption efficiency and facile magnetic separation; however, their synthesis is associated with high cost and secondary environmental impacts. In this study, a novel Mn-Zn ferrite/biochar composite (MZF-BC) is synthesized via a green two-step biocheaching and hydrothermal method using waste batteries and pine sawdust. Characterization results indicate that the introduced Mn-Zn ferrite particles are successfully embedded and coated on biochar (BC), and synthesized MZF-BC50 with 50% BC content exhibits best performance with a specific surface area of 138.5 m2 g-1, the saturation magnetization of 27.5 emu g-1 and CEC value of 53.2 mmol 100 g-1. The maximum adsorption capacity of Pb2+ is 99.5 mg g-1 based on the Langmuir sorption isotherm study at 298 K, and pseudo-second-order model accurately describes the adsorption process. Regeneration test suggests that MZF-BC50 can be efficiently reused for 6 cycles. In addition, it exhibits a good selective Pb2+ and Cd2+ removal performance in lead-acid battery wastewater.